Q.

The correct basicity order of atoms p, q, and r from the following is

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a

q > p > r

b

r > p > q

c

r > q > p

d

p > q > r

answer is B.

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Detailed Solution

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basic nature α1resonance.

 

Morever r is guanidine type of nitrogen.Basicity depends on the negative charge on the nitrogen atom or electron density. With an increase in the -ve charge on the nitrogen atom, the basicity of the amines increases. Basicity depends on charge density. Basicity decreases with a decrease in charge density.Resonance and inductive effects decrease the basicity of an amine.

 

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The correct basicity order of atoms p, q, and r from the following is