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Q.

The correct decreasing order of basicities of following compound is
(I) (CH3CH2)2NH
(II) CH3–CH2–NH2
(III) (CH3)2NH
(IV) Question Image

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a

I > III > II > IV

b

IV > II > III > I

c

II > I > III > IV

d

III > II > I > IV

answer is B.

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Detailed Solution

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I > III > II > IV

 2° - amines are more basic than 1° - amines
 In comp IV, lonepair electron of N is delocalized with Question Image

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