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Q.

The correct decreasing order of priority of functional groups in naming an organic compound as per IUPAC system of nomenclature is :

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a

βˆ’COOR>βˆ’COCl>βˆ’NH2>>C=o

b

βˆ’COOH>βˆ’COOR>βˆ’CONH2>βˆ’COCl

c

βˆ’COOH>βˆ’CONH2>βˆ’COCl>βˆ’CHO

d

 βˆ’SO3H>βˆ’COCl>βˆ’CONH2>βˆ’CN

answer is B.

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Detailed Solution

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The correct decreasing order of priority of functional groups for naming an organic compound in the IUPAC system, as per the table provided, is:

Carboxylic Acid > Ester > Acid Halide > Amide > Nitrile > Aldehyde > Ketone > Alcohol > Thiol > Amine > Benzene (Arene) > Alkene > Alkyne > Alkane > Ether > Alkyl Halide > Nitro

As a numbered list:

  1. Carboxylic Acid
  2. Ester
  3. Acid Halide
  4. Amide
  5. Nitrile
  6. Aldehyde
  7. Ketone
  8. Alcohol
  9. Thiol
  10. Amine
  11. Benzene (Arene)
  12. Alkene
  13. Alkyne
  14. Alkane
  15. Ether
  16. Alkyl Halide
  17. Nitro

This order ensures that when naming a compound, the highest priority group is selected as the principal functional group for the parent name, and others are treated as substituents. This IUPAC ranking is crucial for systematic nomenclature in organic chemistry.

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