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Q.

The correct decreasing priority of ligands NO2,CN,NH2 and CH2NH2 in absolute configuration of an enantiomer is

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a

NO2>NH2>CN>CH2NH2

b

NH2>NO2>CH2NH2>CN

c

NO2>CN>NH2>CH2NH2

d

NH2>NO2>C≡=N>CH2NH2

answer is A.

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Detailed Solution

How the electrons fill these orbitals depends on the strength of the ligand.
One electron fills each orbital before a second one joins in when these are surrounded by weak-field ligands.
The spins of these compounds are high.

The correct decreasing priority of ligands is,

NO2>NH2>CN>CH2NH2

 

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