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Q.

The correct match is

 List-I (Molecule) List-II (Bonds)
A)C2P)1, paramagnetic
B)O2Q)1, diamagnetic
C)B2R)2, paramagnetic
D)Li2S)2, diamagnetic
  T)3, diamgnetic
 (A)(B)(C)(D)
1)RTQP
2)SRPQ
3)SQPR
4)RQTS

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a

1

b

2

c

3

d

4

answer is B.

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Detailed Solution

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C2 : σ1s2σ*1s2σ2s2σ*2s2π2py2π2pz2 B.O=8-42=2 ; diamagnetic

O2 : σ1s2σ*1s2σ2s2σ*2s2σ2px2π2py2π2pz2π*2py1π*2pz1 B.O=10-62=2 ; paramagnetic

B2 : σ1s2σ*1s2σ2s2σ*2s2π2py1π2pz1 B.O=6-42=1 ; paramagnetic

Li2 : σ1s2σ*1s2σ2s2 B.O=4-22=1 ; diamagnetic

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