Q.

The correct match is

 Molecule Shape
A)CO32-P)Pyramidal
B)SO42-Q)Tetrahedral
C)ClO4-R)Linear
D)ClO3-S)Trigonal planar
 (A)(B)(C)(D)
1)QSPR
2)RPRS
3)PRSQ
4)SQQP

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a

2

b

1

c

3

d

4

answer is D.

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Detailed Solution

detailed_solution_thumbnail

no.of hybrid orbitals(H.O)=12V+M-charge

CO32-: no. of H.O=124+2=3sp2 hybridizationtrigonal planar

SO42-: no. of H.O= 126+2=4sp3hybridization Tetrahedral

ClO4- : no. of H.O= 127+1=4sp3hybridization Tetrahedral

ClO3-: no. of H.O= 127+1=4sp3hybridization pyramidal, due to a lonepair

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