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Q.

The correct option for the value of vapour pressure of a solution at 45oC with benzene to octane in molar ratio 3 : 2 is :
[At 45oC vapour pressure of benzene is 280 mm Hg and that of octane is 420 mm Hg. Assume Ideal gas]

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a

336 mm of Hg

b

160 mm of Hg

c

350 mm of Hg

d

168 mm of Hg

answer is D.

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Detailed Solution

Applying Raoult’s law, Ptotal =PA0XA+PB0XB
XA=35,XB=25Ptotal =280×35+420×25=336mm of Hg

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