Q.

The correct option(s) about entropy (S) is(are)

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a

The cell reaction,  Ag|Ag+(0.1M)||Ag+(0.2M)|Ag , is an entropy driven process.

b

ΔS>0 for micellization.

c

For racemization of an optically active compound,  ΔS<0.

d

For the reaction, 2Al(s)+6H+(aq) 2Al3+(aq)+3H2(g), if dEcelldT=2R3F , then the entropy change of the reaction is 4R. 
 

answer is A, B, D.

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Detailed Solution

A)  ΔS=nFdEdt=6F×2R3F=4R
B) The cell is spontaneous and there is decrease in concentration on moving from reactant side to product side and hence  ΔS>0
Ag+(0.2M) Ag+(0.1M)E=0.061log0.10.2>0
C) Racemization leads to increase in entropy as randomness increases.
D)  ΔS>0 for micellization due to release of solvated water molecules from the hydrophilc head of surfactant molecules.

 

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