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Q.

The correct order in aqueous medium of basic strength in case of methyl substituted amines is:

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a

${M e}_{2} N H > {M e N H}_{2} > {M e}_{3} N > {N H}_{3}$

b

${M e}_{2} N H > {M e}_{3} N > {N H}_{3} > {M e N H}_{2}$

c

${N H}_{3} > {M e}_{3} N > {M e N H}_{2} > {M e}_{2} N H$

answer is A.

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Detailed Solution

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In aqueous medium basic strength is dependent on electron density on nitrogen as well as solvation of cation formed after accepting H. After considering all these factors overall basic strength order is ${N H}_{3} > {M e}_{3} N > {M e N H}_{2} > {M e}_{2} N H$

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