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Q.

The correct order of acidic nature of protons in the following compound is

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a

I < II < III

b

III < I < II

c

II < III < I

d

III < II < I

answer is C.

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Detailed Solution

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When (I) proton is removed, the negative charge participates in resonance, leading to a negative charge on more electronegative atom i.e. oxygen resulting in a highly stabilized conjugate base.

When (II) proton is ejected, the extent of resonance is less due to cross conjugation with two double bonds.

When (III) proton is extracted, the extent of resonance is more compared to (II) proton.

Thus, the order of acidic nature of protons in the following compound is: II < III < I.

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