The correct order of acidic nature of the oxides of chlorine is :

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${Cl}_{2} O < {ClO}_{2} < {Cl}_{2} O_{6} < {Cl}_{2} O_{7}$

${Cl}_{2} O < {ClO}_{2} < {Cl}_{2} O_{7} < {Cl}_{2} O_{6}$

${ClO}_{2} < {Cl}_{2} O < {Cl}_{2} O_{6} < {Cl}_{2} O_{7}$

${Cl}_{2} O_{7} < {Cl}_{2} O_{6} < {ClO}_{2} < {Cl}_{2} O$

answer is A.

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Detailed Solution

The oxidation state is proportional to the acidic nature.

The oxidation state of ${CI}_{2} O$ is +1.
The oxidation state of ${CIO}_{2}$ is +4.
The oxidation state of ${CI}_{2} O_{6}$ is +6.
The oxidation state of ${CI}_{2} O_{7}$ is +7.

Thus ,The correct order of acidic nature of the oxides of chlorine is

${Cl}_{2} O < {ClO}_{2} < {Cl}_{2} O_{6} < {Cl}_{2} O_{7}$ .

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