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Q.

The correct order of basic strength of the following are

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a

III > IV > II > I

b

IV > II > III > I

c

I > II > III > IV

d

III > II > IV > I

answer is D.

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Detailed Solution

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Amines are more basic 

In III lone pair is not in conjugation and lone pair electrons are readily available for protonation and is more basic

In II due to +M effect of OH group lone pair electrons on N is less readily involved in conjugation with C=O group and more readily available for protonation 

In I lone pair electrons on N atom is readily involving in resonance with benzene ring and not available for protonation

Basic strength order is III > II > IV > I

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