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Q.

The correct order of basicities of the following compounds is

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a

CH3CH2NH2

b

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c

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d

CH32NH

answer is B.

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Detailed Solution

Here, compound 1 is more basic because more no. of N atoms on same carbon atom that leads more basic nature. 2°amines are more basic than 1°amines. Hence, 3>2 . In acetamide, lone pair electrons involve in delocalization and it makes that basicity decreases.

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Therefore, the correct order of basicity of compounds is 1>3>2>4.

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