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Q.

The correct order of basicity of the following compounds is:

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a

3 > 1 > 2 > 4

b

1 > 2 > 3 > 4

c

2 > 1 > 3 > 4

d

1 > 3 > 2 > 4

answer is B.

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Detailed Solution

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Among given the order of Basicity isQuestion Image

Based on I effect & electron density.Basicity depends on the negative charge on the nitrogen atom or electron density. With an increase in the -ve charge on the nitrogen atom, the basicity of the amines increases. Basicity depends on charge density. Basicity decreases with a decrease in charge density.Resonance and inductive effects decrease the basicity of an amine. Except in the case of guanidine, where nitrogen gains negative charge. Plus I effect will increase the basicity.

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The correct order of basicity of the following compounds is: