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Q.

The correct order of boiling point of ${NCl}_{3}, {NClF}_{2}, {NF}_{3}$ is :

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a

${NCl}_{3} < {NClF}_{2} < {NF}_{3}$

b

${NClF}_{2} < {NCl}_{3} < {NF}_{3}$

c

${NCl}_{3} < {NF}_{3} < {NClF}_{2}$

d

${NCl}_{3} > {NClF}_{2} > {NF}_{3}$

answer is A.

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Detailed Solution

The correct order of boiling point of ${NCl}_{3}, {NClF}_{2}, {NF}_{3}$ is :

${NCl}_{3} > {NClF}_{2} > {NF}_{3}$ ,

The boiling point of NH3 is higher (–33˚C) while the boiling point of NCl3 (71˚C) is lower.

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