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Q.

The correct order of decreasing basic strength of the following amine is

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a

I>II>III>IV

b

I>IV>II>III

c

IV>I>III>II

d

IV>I>II>III

answer is D.

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Detailed Solution

I….. l.p is not involved in resonance --- most Basic  I, III, IV ….. l. p is involved in the resonance…. Less basic NO2(I,M)  Basic strength. 

CH3+I+H Basic strength.

In compound, I, lone pairs are not involved in resonance, so basic strength is highest. In compound IV, because of present of -Me group, its basic strength is high. In compound II, there is only one -NH2 group whose lone pairs involved in resonance, hence its basic strength less than compound IV. At last, because of presence of -NO2 group, basic strength of III is the lowest.

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