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Q.

The correct order of electron gain enthalpy gain enthalpy with negative sign of F, Cl, Br and I, having atomic number 9, 17, 35 and 53 respectively, is:

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a

F>Cl>Br>I

b

Cl>F>Br>I

c

Br>Cl>I>F

d

I>Br>Cl>F

answer is B.

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Detailed Solution

As we move down in a group electron gain enthalpy becomes less negative because  the size of the atom increases and the distance of added electron from the nucleus increases. Negative electron gain enthalpy of F is less than Cl. This is due to the fact that when an electron is added to F, the added electron goes to the smaller n = 2 energy level and experience significant repulsion from the other electrons present in this level. In Cl, the electron goes to the larger n = 3 energy level and consequently occupies a larger region of space leading to much less electron repulsion. So, the correct order is  Cl>F>Br>I

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