Q.

The correct order of energies of molecular orbitals of N2 molecule, is

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a

σ Is <σ 1s <σ2s<σ2s<π2px=π2py<π2px=π2py<σ2pz<σ2pz

b

σ ls <σ 1s <σ2s<σ2s<σ2pz<π2px=π2py<π2px=π2py<σ2pz

c

σ ls <σ 1s <σ2s<σ2 s <π2px=π2py<σ2pz<π2px=π2py<σ2pz

d

σ Is <σ 1s <σ2s<σ2s<σ2pz<σ2pz<π2px=π2py<π2px=π2py

answer is B.

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Detailed Solution

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Formolecules having 14e

σ1s<σ1s<σ1s<σ2s<π2px=π2py<σ2pz<(π2px=π2px)<σ2pz

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The correct order of energies of molecular orbitals of N2 molecule, is