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Q.

The correct order of hybridisation of the central atom in the following species; Ni(CN)42,XeO4 and SF4 and  NO3 is : 

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a

dsp2,sp3d,sp3,sp2

b

dsp2,sp3,sp3d,sp2

c

sp3,dsp2,sp3d,sp2

answer is B.

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Detailed Solution

The Ni(CN)4 has the electrical configuration 3d84s0 in the valence shell. All of the electrons are coupled up in the presence of CN- ions with a strong field. Through dsp2 hybridization, the empty 3d, 3s, and two 4p orbitals are created.
In order to create XeO4, xenon must go through sp3 hybridization in its fourth excited state. state of fourth excitement.
SF4hybridises in an sp3d manner.
NO3- hybridization is of the sp2 kind.

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