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Q.

The correct order of increasing basic nature for the bases NH3, CH3NH2 and  (CH3)2NH is:

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a

CH3NH2<NH3<(CH3)2NH

b

CH3NH2<(CH3)2NH<NH3

c

NH3<CH3NH2<(CH3)2NH

d

(CH3)2NH<NH3<CH3NH2

answer is C.

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Detailed Solution

The alkyl groups donate electrons to the nitrogen atom by +I effect. Among the amines, secondary amines are more basic than primary amines. So, the correct order of increasing basic nature of bases in aqueous solution is NH3<CH3NH2<(CH3)2NH.

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