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Q.

The correct order of increasing extent of hydrolysis is

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a

CCl4<SiCl4<PCl5<AlCl3<MgCl2

b

CCl4<AlCl3<MgCl2<PCl5<SiCl4

c

CCl4<PCl5<SiCl4<AlCl3<MgCl2

d

CCl4<MgCl2<AlCl3<SiCl4<PCl5

answer is A.

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Detailed Solution

Aqueous hydrolysis of CCl4 is not possible due to absence of vacant orbital in carbon, while hydrolysis of MgCl2, AlCl3, SiCl4 and PCl5 is possible. Ease of hydrolysis is proportional to the ease of attack of H2O molecule on central atom.

CCl4<MgCl2<AlCl3<SiCl4<PCl5

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The correct order of increasing extent of hydrolysis is