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Q.

The correct order of rate of addition of Br2/ water to the following alkenes is
CH2=CH2      CH2=CHNO2      [A]                                           [B]
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a

[D] > [C] > [A] > [B]

b

[A] > [B] > [D] > [C]

c

[D] > [C] > [B] > [A]

d

[A] > [B] > [C] > [D]

answer is A.

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Detailed Solution

D has 2 alkyl groups, C has one and A has none, but the B has a  electron with drawing nitro group.  So, higher the stability of 
 bromonium ion formed higher be the rate of bromination reaction. So the correct order of rate of  reaction is D>C>A>B
 

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