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Q.

The correct order of reactivity of the following compounds towards SN1 reaction is 
I)   CH3CH2X            II) (C6H5) 2CH2X
III) (CH3) 3CX        IV) (CH3) 2CHX

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a

II > III > IV > I

b

IV > III > I > II 

c

I > IV > III > II

d

I > IV > II > III 

answer is B.

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Detailed Solution

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Reactivity order in SN1 reactions: Benzyl R-X > 3o R-X > 2o R-X > 1o R-X.

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