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Q.

The correct order of stability

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a

H2>He2+>H2+>He2

b

H2>H2+>He2+>He2

c

H2>H2+>He2>He2+

answer is C.

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Detailed Solution

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H2: σ1s2 ; B.O=2-02=1 H2+: σ1s1 ; B.O=12=0.5 He2 : σ1s2σ*1s2 ; B.O=2-22=0 He2+ :  σ1s2σ*1s1 ; B.O=12=0.5

As bond order increases, stability increases.

Bond order for both H2+ and He2+​ is same but H2+ is more stable than He2+​ due to absence of electrons in anti-bonding orbital.

Hence, H2>H2+>He2+>He2.

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