Q.

The correct order of the calculated spin only magnetic moments of complexes (A) to (D) is:

(A) Ni(CO)4 (B) [Ni(H2O)6]Cl2 (C) Na2[Ni(CN)4] (D) PdCl2(PPh3)2

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a

(A) (C) (D)<(B)

b

(C) (D)<(B)<(A)

c

(C) < (D) < (B) < (A)

d

(A) (C)<(B) (D)

answer is A.

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Detailed Solution

 NiCO4,Na2NiCN4 and PdCl2PPh32 are diamagnetic with zero magnetic moment due to pairing of electrons  by strong field ligands         A= C = D < B

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