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Q.

The correct order of the spin-only magnetic moments of the following complexes is :
(I) CrH2O6Br2
(II) Na4Fe(CN)6
(III) Na3FeC2O43Δ0>P

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a

 (III) > (I)  > (II) 

b

 (I)  > (III) > (II) 

c

 (II) (I)>( III )

d

 (III) > (I) > (II)

answer is B.

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Detailed Solution

(I) [Cr(H2O)6]2+ Cr2+= [Ar]3d4 H2Ois a weak field ligand  

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4 unpaired electrons 

Magnetic moment μ=24 = 4.89BM 

(II)[Fe(CN)6]4- Fe2+=[Ar]3d6 CN- is a strong field ligand   

Question Image

 

 

 

 

Unpaired electrons = 0 

magnetic moment = 0 

(III)[Fe(C2O4)3]3- Fe3+= [Ar]3d5 As   Δ0  >  P 

Question Image

 

 

 

 

Nummber of unpaired electron = 1 

Magnetic moment μ=1(1+2) =1.732BM

(IV)(EtN)+(CoCl4) Co2+=[Ar]3d7  

Question Image

 

 

 

 

Number of unpaired electrons=3 

Magnetic moment μ=3(3+2) =3.87BM

 

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