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Q.

The correct order of 0 value of the give complexes is :

(I) [Co(H2O)6]3+     (II) [CoF6]3-     (III) [Co(NH3)6]3+     (IV) [Co(CN)6]3-

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a

III < II < I < IV

b

II < I < IV < III

c

I < II < III < IV

d

II < I < III < IV

answer is C.

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Detailed Solution

F¯  H2O NH3  CN¯

 Intensity of ligands increases (electron donating ability) 

0  (CSFE) increases

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