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Q.

The correct order of N-Obond length in NO,NO2- and NO3- will be

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a

NO>>NO2>NO3-

b

NO3->NO2->NO

c

NO2->NO3->NO

d

NO>NO3->NO2-

answer is C.

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Detailed Solution

Nitrogen atom has 2+5=7 electrons
Oxygen atom has 2+6=8 electrons
Now NO has 6 electrons in the bonding and 1 in the antibonding.
NO2+has 2 electrons lesser than NO; So 6 electrons in the bonding and no electrons in the antibonding.

 Thus, NO2+, Bond Order =6-02=3  For NO2,Band order =632=1.5  For NO3, Band order =642=1  The order of Band order is :  NO3>NO2>NO2+

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