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Q.

The correct relationship between molarity (M) and molality (m) is (d= density of the solution, in KgL-1,M2= molar mass of the solute in kg mol-1 )

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a

M=m1+mM2 d

b

M=1+mdmM2

c

M=1+mM2md

d

M=md1+mM2

answer is A.

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Detailed Solution

We know that

Molarity (M)=No. of moles of soluteVolume of solution{ in litres}

Molality (m) =No. of moles of soluteweight of solvent

If a be density in g/cm3.

Then mass of the solution =1000d gm

mass of solute =M×M2

where M2= molar mass of solute

Mass of solvent =1000 d-MXM2

 Molality(m)=M×10001000d-M×M2

M=md1+mM2

Hence, option (a) is the answer.

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