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Q.

The correct set(s) of order is/ are:

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a

LiCl<BeCl2<BCl3<CCl4 (covalent character)

b

Be(OH)2<Mg(OH)2<Ca(OH)2<Sr(OH)2<Ba(OH)2 (water solubility)

c

XeF4<H2O<NH3<BF3 (bond angle)

d

sp3<sp2<sp(%character )

answer is B, A, C, D.

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Detailed Solution

1) The covalent character increases as the cation size decreases.
As a result, covalent character rises from  .
2) Since, lattice energy is inversely proportional to solubility. So,  
3)Three bond pairs and one lone pair is used for the pyramidal structure of NH3. A bond angle of  exists.
Trigonal planar shape and three bond pairs characterise BF3. So, Bond angles measure  .
4) In sp, sp2 and sp3 hybridised carbon, the proportion of the s character is 50%, 33.33%, and 25%, respectively.
XeF490<H2O104.5<NH3107<BF3120.

The correct option is A,B,C,D.

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