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Q.

The correct statement among the following is

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a

The colour of 
Cr2O72-ion is due to d-d tran-
sition of unpaired electrons

b

 Transition elements form a large number
of alloys, because of similar boiling points

c

Bronze is an alloy of Copper and Zinc

d

Salt of Fe+2 ion has greenish colour

answer is C.

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Detailed Solution

1) The color of Cr2O72-ion is basically due to the ligand metal charge transfer. There is no unpaired electron of Cr is present in the 3d and 4s orbitals of Cr

2) The transition metals can easily form alloys because they have very similar atomic sizes which leads their nature towards alloy formation. As they are having very similar atomic sizes, a metal can replace another metal from its lattice and create a solid solution. 

3) Bronze is an alloy of Cu and Zn.

4) Fe+2 salt has pale blue/ green color.

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