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Q.

The correct statement of the following is :

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a

The species CuCl42exists but CuI42 does not.

b

Both copper (I) and copper (II) salts are known in aqueous solution.

c

FeI3 is stable is aqueous solution.

d

An acidified solution of K2CrO4 gives yellow precipitate on mixing with lead acetate.

answer is C.

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Detailed Solution

I- ion is a stronger reducing agent therefore, it reduces Fe3+ to Fe2+ at room temperature. Therefore, FeI3 is not stable.

2FeI32FeI2+I2

Lead acetate forms yellow ppt with K2Cr2O7 without presence of any acid or in the absence of the acidic medium

Pb(CH3COO)2+K2Cr2O7PbCrO4Yellow ppt+2CH3COOK

Iodide ion has a large size and is a strong reducing agent. So, when copper cation comes in contact with iodide anion, iodide get oxidized to iodine molecule and formation of complex is not takes place

In aqueous solution, Cu and Cu2+ are present but not Cu+.

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The correct statement of the following is :