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Q.

The correct statement(s) about the oxoacids, HClO4 and HClO , is(are)

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a

HClO4 is more acidic than HClO because of the resonance stabilization of its anion

b

HClO4 is formed in the reaction between Cl2 and H2O

c

The central atom in both HClO4 and HClO is sp3 hybridized

d

The conjugate base of HClO4 is weaker base than H2O 

answer is A, C, D.

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Detailed Solution

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(A) HClO4 H++ClO4

HClO H++ClO

ClO4 is resonance stabilized anion

HClO4 is more acidic than HClO

(B)  Cl2+H2O HClO+HCl

(C)  HClO4 Question ImageCentral is sp3 hybridised

HClOQuestion ImageCentral atom is sp3 hybridised

(D)  HClO4+H2OH3O+ClO4 since H2O is accepting H+ from HClO4 so H2O is stronger basic compare to ClO4

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