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Q.

The correct statement(s) among the following is/are

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a

Ionization energy of  N2  molecule is more than that of C2   as well as O2molecules

b

From  N2  molecule the energy required to remove an electron from  σ2Pz  is less than to remove an electron from π2Py  or  π2Px 

c

O–O bond is weaker than S–S bond but O=O bond is stronger than S=S

d

Bond energy of N2+  is more than that of  N2

answer is A, B, C, D.

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Detailed Solution

IP of N2 (15.58 eV) is more than C2 (12.4 eV) and O2 (12.07 eV). Due to repulsion by non–bonding electron pairs in O2 the O–O single bond energy is less but due to small size  pπpπ   bond in O2 is strong. Due to the presence of electron in anti bonding MO in  N2   bond energy is less than that of  N2+ 

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