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Q.

The correct statement with respect to these complexes

Ni(CO)4 and Ni(CN)42 is

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a

Nickel is in the same oxidation state in both

b

Both have tetrahedral geometry

c

Both have square planar geometry 

d

Have tetrahedral and square planar geometry respectively 

answer is D.

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Detailed Solution

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Hybridization of nickel in Ni(CO)4 is sp3 therefore geometry of  Ni(CO)4 is tetrahedral whereas hybridization of nickel in

Ni(CN)42 is dsp2 therefore geometry of Ni(CN)42 is square planar. 

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