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Q.

The correct statements about ICl4 and IO4 is/ are

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a

IO4 can act as weaker oxidizing agent than ICl4

b

IO4 is tetrahedral but ICl4 is square planer

c

ICl4 is a polyhalide ion but IO4 is an oxoanion

d

ICl4 contain only single bonds but IO4 contain only double bonds

answer is B, C.

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Detailed Solution

Periodates are stronger oxidizing agents ICl4 have square planar structure with two lone pairs occupying the opposite corners of octahedron ICl4 ion is formed by the addition of Cl ion to ICl3. So it is polyhalide. IO4 is oxoanion of oxoacid HFO4. I-Cl bonds in ICl4 are only single bonds but the I-O bonds in IO4 are 3 double and one single bonds 

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