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Q.

The correct statements among (a) to (d) are :
1. Saline hydrides produce H2 gas when reacted with H2O
2. Reaction of LiAlH4 with BF3 leads to B2H6
3. PH3 and CH4 are electron rich and electron precise hydrides, respectively
4. HF and CH4 are called as molecular hydrides

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a

(1), (2), (3) and (4)

b

(1), (3) and (4) only

c

(1), (2) and (3) only

d

(3) and (4) only

answer is B.

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Detailed Solution

MH+H2OMO+H24AlH4+4BF3 Ether2B2H6+3LiF+3AlF3
PH3 is electron rich and CH4 is electron precise hydride CH4 both are molecular hydride but HF is covalent hydride.

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