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Q.

The correct statements among the following are

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a

The complexes NiCl42 and Ni(CN)42differ in the geometry

b

The complexes NiCl42 and Ni(CN)42differ in primary valencies of nickel

c

The complexes NiCl42 and Ni(CN)42 differ in the state of hybridisation

d

The complexes [NiCl4)2– and [Ni(CN)4]2– differ in the magnetic propertic

answer is A, B, D.

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Detailed Solution

[NiCl4]2– - sp3, two unpaired e [Ni (CN)4]2– - dsp2 no unpaired e

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