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Q.

The correct statements among the following is/are

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a

Most five-coordinate compounds adopt either the Trigonal bipyramidal (TBP) or square pyramidal(SP structures).

b

When the central atom is a main group element, the axial bonds are longer than the equatorial bonds in TBP structure but reverse is the case for the SP structure

c

When the central atom is a transition element in TBP (ex.  CuCl53) the axial CuCl  bonds are shorter than equatorial ones but on the other hand in sp  (ex.  Ni(CN)53)  the axial NiC  bonds are longer than the equatorial ones.

d

In BrF5  the bromine atom is below the basal plane of square pyramid but in  Ni(CN)53 the  Ni  atom is above the basal plane

answer is A, B, C, D.

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Detailed Solution

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The situation in B is well known and may be explained in terms of  sp3d hybridization or the VSEPR theory.
For Ni(CN)53  in (C) the highest d-orbital dx2y2  is empty, thus allowing the basal lingads to move in closer to the metal. For CuCl53  the highest d-orbital dz2   is only half filled leading to shorter axial bonds.
The lone pair in  BrF5  is below the basal plane and repel the in-plane ligands upward. On the other hand no such effect is found in Ni(CN)53 . In addition ligands repulsions will force the basal ligands downward.

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