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Q.

The correct statements among the following is/are

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a

Among the addition compounds formed by NO  with halogens,  FNO,ClNO and  BrNO, the NO bond length is shortest in FNO and longest in BrNO

b

Among the FNO,ClNO and BrNO  the bond angle is lowest in FNO  and largest in BrNO

c

Some metals are found in nature as their oxides whereas others (heavier metals such as lead mercury etc.) are found as sulphides

d

The bond angles in H2O,HOF and OF2 are in the order  H2O>OF2>HOF

answer is A, B, C, D.

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Detailed Solution

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A) Electron affinity of oxygen is least among the oxygen family elements and thus its formation O2 is more endothermic
B)  SF6 is non-polar while in SF4 is polar
C) Due to steric hindrance SF6 is chemically inert
D) SOCl2 is the chloro derivatives of H2SO3 while SO2Cl2 is the chloro derivative of H2SO4

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