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Q.

The correct statement(s) pertiaining to the adsorption of a gas on a solid surface is (are) 

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a

Physisorption may transform into chemisorption at high temperature

b

Adsorption is always exothermic

c

Chemisorption is more exothermic than physisorption, however it is very slow due to higher energy of activation

d

Physisorption increases with increasing temperature but chemisorption decreases with increasing temperature

answer is A, B, D.

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Detailed Solution

 (a) ΔH=ve for adsorption

 (b) Fact 

(d) Chemical bonds are stronger than vander waal's forces so chemical adsorption is more exothermic.

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The correct statement(s) pertiaining to the adsorption of a gas on a solid surface is (are)