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Q.

The correct structures & names of ‘Z’ in the following

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a

Z = Methionine 

b

Z = cysteine

c

Z= Alanine                                  

d

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answer is A, B.

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Detailed Solution

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  1. Starting compound:
    Aromatic ring –OH with substituents:

    • COOCH₂CH₃

    • CH₂CH₂SMe

    Reaction with R–CH(COOC₂H₅)₂

    Pathway arrow labeled [a] pathway

  2. Intermediate with aromatic ring –OH and COOCH₂CH₃, COOCH₂CH₃ substituents

  3. Further intermediate with COOCH₂CH₃ and CH₂CH₂SMe

  4. Final product (labeled (I)):
    Aromatic ring –OH, COOCH₂CH₃, COOCH₂CH₃ and CH₂CH₂SMe

 

 

Reaction with NH₂CH leads to new intermediate structure.

 

 

  • Structure of Phthalic acid

  • Final product (after hydrolysis H₃O⁺):

    • COOH

    • NH₃⁺ – CH(COOC₂H₅) – CH₂CH₂SMe

    → Results in an amino acid derivative.

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The correct structures & names of ‘Z’ in the following