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Q.

The correct structures of trans - [NiBr2(PPT3)2] and meridonial - [Co(NH3)3(NO2)3], respecti-vely, are :

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a

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b

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c

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d

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answer is B.

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Detailed Solution

  • [NiBr2(PPT3)2] ,it is square planar complex it exists as cis or trans only here it is trans.

 [Co(NH3)3(NO2)3], it is an octahedral complex, in this when three ligands are identical, it shows facial (3 ligands on same face)or meridional isomers(2 ligands at 90° 1 ligand at 180°).

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