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Q.

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The correct systematic name of the above compound is :

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a

3-methoxy formyl ethanoic acid

b

2-methoxy formyl acetic acid

c

2-acetoxy ethanoic acid

d

3-methoxy carbonyl propanoic acid

answer is B.

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Detailed Solution

The correct systematic (IUPAC) name of the compound shown in the image:

Structural formula: CH₃–O–C(=O)–CH₂–COOH

This is a compound where a methyl group is attached via oxygen to a carbonyl (making it a methyl ester), and a carboxylic acid group is present on the second carbon.

Breaking Down the Structure

  • Parent chain: 2 carbons, so the parent acid is propanoic acid.
  • Methyl ester function is present at the first carbon.
  • Correct systematic name is: Methyl 2-carboxyacetate or, by standard IUPAC naming, Methyl 2-carboxyacetate.
  • More strictly, since the main chain has two carboxylic acid groups (one as ester, one free), the preferred IUPAC name is Methyl 2-carboxyacetate, but the most accepted and commonly used IUPAC name is:

Methyl 2-carboxyacetate or Methyl malonate (malonic acid monomethyl ester).

Final IUPAC Name:

Methyl 2-carboxyacetate

or

Methyl malonate (monomethyl malonate).

For competitive exams and standard nomenclature:

Methyl 2-carboxyacetate is the best answer.

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