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Q.

The correct thermodynamic conditions for the non - spontaneous reaction at all temperatures is

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a

rH <0;rS < 0                   

b

rH >0;rS > 0

c

rH >0;rS < 0

d

rH <0;rS < 0

answer is B.

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Detailed Solution

rH >0, energy term is not favouring

rS < 0 entropy term is not favouring

G=H-TS = +ve

system is non-spontaneous under all temperatures

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