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Q.

The correct thermodynamic conditions for the spontaneous reaction at all temperatures is

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a

ΔH<0 and ΔS>0

b

ΔH>0 and ΔS<0

c

ΔH<0 and ΔS=0

d

ΔH<0 and ΔS<0

answer is C.

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Detailed Solution

The correct thermodynamic conditions for the spontaneous reaction at all temperatures is

H<0 and S>0

Under these conditions, ΔG=ΔH-TΔS<0

The correct thermodynamic conditions for the spontaneous reaction at all temperatures is H<0 and S>0

Under these conditions, ΔG=ΔH-TΔS<0

Note: for spontaneous reactions, ΔG<0, for non spontaneous reactions, ΔG>0, for reactions at equilibrium, ΔG=0

Hence the correct answer is (C) ΔH<0 and ΔS>0.

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