Q.

The correct value of cell potential in volt for the reaction that occurs when the following two half cells are connected, is
Fe(aq) 2++2eFe(s),E=0.44VCr2O72 (aq) +14H++6e2Cr3++7H2O, E=+1.33V

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a

+1.77V

b

+0.01V

c

+0.89V

d

+2.65V

answer is A.

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Detailed Solution

Anode: FeFe2++2e
Cathode: Cr2O72+14H++6e2Cr3++7H2O
Ecell =Ecathode E anode =1.33(0.44)=+1.77V

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