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Q.

The correct van der Waals equation for 1 mole of a real gas is :

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a

p+aV2(V−b)=RT

b

p+an2V2V2−nb=RT

c

p+V2a(V−b)=RT

d

p+a2V(V−nb)=nRT

answer is A.

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Detailed Solution

p=pi+av2for 1 mole of gas
V = (v-b)
∴pi+av2[v−b]=RTfor 1 mole of gas

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The correct van der Waals equation for 1 mole of a real gas is :