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Q.

The d-electron configuration of [Ru(en)3]Cl2 and [Fe(H2O)6] Cl2 respectively are:

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a

t2g4eg2and  t2g6eg0

b

t2g6eg0and  t2g4eg2

c

t2g4eg2and  t2g4eg2

d

t2g6eg0and  t2g6eg0

answer is B.

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Detailed Solution

Fe and Ru belong to same group and their ions Fe2+ and Ru2+  in the given complex have d6configuration. In Ruen3Cl2, the electrons rearrange having t2g6eg0. In  FeH2O62+since  H2O is weak ligand electrons do not rearrange. So have t2g4eg2.

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The d-electron configuration of [Ru(en)3]Cl2 and [Fe(H2O)6] Cl2 respectively are: