Q.

The decomposition of benzene diazonium chloride in aqueous solution is a reaction of first order which proceeds as C6H5N2Cl → C6H5Cl + N2 (g) . A certain solution of benzene diazonium chloride contains initially an amount of this compound which gives 80 cm3 of nitrogen on complete decomposition. It is found that at 300C, 40cm3 of nitrogen are evolved in 40 minutes. How long (in min) after the start of the decomposition, will 70cm3 of nitrogen have been evolved (log 2 = 0.3010)

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answer is 120.

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Detailed Solution

k=1tlnvvvt=constant140ln808040=1tln808070t=120min

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